李扬
时间:2018-10-21      点击:

李扬,男,汉族,博士,毕业院校:陕西师范大学,职称:副教授。

邮箱liyang@xpu.edu.cn

研究方向:有机氟化学

科研情况:

1:国家自然科学基金青年项目:镍催化含氟烯烃参与的Heck反应研究。(2016-2018,研究经费21万)主持

2:中国博士后基金面上项目二等资助:镍催化含氟烯烃参与的Heck反应研究。(2016-2017,研究经费5万)主持

3:陕西省重点研发计划项目:高效含氟清洗剂的研制及其工程化。(2017-2019, 45万)主持

4:西安工程大学青年拔尖人才项目(2018-2020, 20万)主持

自2010年以来,一直从事金属有机合成的研究工作。在过渡金属催化的碳氟键构筑和氟化学等方面具有一定的研究基础。对相关研究的热点、难点以及发展动向具有深刻的认识。先后在Org LettChem CommunOrg Biomol ChemJ Org ChemRSC AdvanceEur. J. Org. Chem等国际学术期刊发表SCI论文近20篇。担任Green ChemistryRSC Advances等杂志审稿人。

1:Yang Li*, Lan-Ting Shi, Wen-Qing Zhu, Hong Li, Qiang Zhang,Transition-metal-free Efficient Synthesis of Bisindole Sulfanes Using 2-(Fluorosulfonyl)difluoroacetic Acid.Synlett. 2018, 29, 1847-1850. (SCI, IF = 2.2).

2:Yang Li, Dong-Huai Tu, Bo Wang, Yao-Yu Wang, Zhao-Tie Liu, Zhong-Wen Liu, Jian Lu. Nickel-catalyzed carbonylation of arylboronic acids with DMF as CO source.Org. Chem. Front.2017, 4, 569-572. (SCI, IF = 5.0)

3:Yang Li, Dong-Huai Tu, Yu-Jie Gu, Bo Wang, Yao-Yu Wang, Zhao-Tie Liu, Zhong-Wen Liu, Jian Lu. Palladium-catalyzed Suzuki-Miyaura reaction of fluorinated vinyl chloride: a new approach for synthesis α and α,β-trifluoromethylstyrenes.Tetrahedron, 2016, 72, 5684–5690 (SCI. IF = 2.6).

4:Yang Li, Dong-Huai Tu, Yu-Jie Gu, Bo Wang, Yao-Yu Wang, Zhao-Tie Liu,Zhong-Wen Liu, Jian Lu. Oxidative Heck Reaction of Fluorinated Olefins with Arylboronic Acids by Palladium Catalysis.Eur. J. Org. Chem.2015, 4340–4343 (SCI. IF = 3.0).

5:Yang Li, Dong Xue, Wei Lu, Chao Wang and Jianliang Xiao. Rh-Catalyzed methylation of ketones: DMF as a Carbon source .Org. Lett.2014, 16, 66-69 (SCI,IF = 6.8)

6:Yang Li,Dong Xue, Chao Wang, Zhao-Tie Liu and Jian-Liang Xiao. Carboxylic acid anhydrides via Pd-catalyzed carbonylation of aryl halides at atmospheric CO pressure. Chem. Commun.2012, 48, 1320–1322 (SCI, IF = 6.5)

7:Yang Li, Dong Xue, Wei Lu, Xiaogang Fan, Chao Wang and Jianliang Xiao. 3-Acylindoles via palladium-catalyzed regioselective arylation of electron-rich olefins with indoles.RSC Adv., 2013, 3, 11463-11466 (SCI,IF = 3.2)

8 :Yang Li,Wei Lu, Dong Xue, Chao Wang and Jianliang Xiao, Palladium-catalyzed carbonylation of benzeneboronic acid for preparing ketones.Synlett.2014, 25, 1097-1100(SCI,IF = 2.3)

9: Dong-Huai Tu,Yang Li, Bo Zhao, Yu-Jie Gu, Bo Wang, Ju-You Lu, Jian Lu.Nickel-Catalyzed Addition of Arylboronic Acids to Alkyl Nitriles for Synthesis of Aryl Ketones in Fluorinated Solvent, Synlett, DOI: 10.1055/s-0036-1589137.

10:Kun Dai,Kuan Wang,Yang Li,Jian-Gang Chen,Zhong-Wen Liu,Jian Lu,Zhao-Tie LiuConstruction of β-Trifluoromethyl Enol Ether via Base-Promoted C–O Coupling and Rearrangement of Hydrogen Atom,J. Org. Chem.,2017,82, 4721-4728.

11: Dong-Huai Tu,Yang Li,JiangweiLi,Yu-Jie Gu,Bo Wang,Zhao-Tie Liu,Zhong-Wen Liu,Jian Lu.Selective oxidation of arylalkanes with N-Graphitic-Modified cobalt nanoparticles in water,Catalysis Communications, 2017, 97, 130-133.

12: Fan Pu,Yang Li, Yong-Hong Song, Jianliang Xiao, Zhong-Wen Liu, Chao Wang, Zhao-Tie Liu, Jian-Gang Chen, Jian Lu, Copper-Catalyzed Coupling of Indoles with Dimethylformamide as a Methylenating Reagent, Adv. Synth. Catal., 2016, 358,539-542.

13:Bo Zhao,Yang Li,Dong-Huai Tu,Wei Zhang,Zhao-Tie Liu,Jian Lu, Palladium catalyzed mono and difunctionalization of hexafluorobut-2-yne, Tetrahedron Lett., 2016, 57, 4345-4347.

14:Jian-Ping Kang,Ju-You Lu,Yang Li,Zhi-Xuan Wang,Wei Mao,Jian Lu,Atom-economical synthesis of 3,3,3-trifluoropropanal dialkyl acetals through Pd/C catalyzed acetalization of 3,3,3-trifluoropropene,RSC Adv.,2016,6, 39387-39391.

15: Bo Zhao, Ju-You Lu,Yang Li, Dong-Huai Tu, Zhao-TieLiu, Zhong-Wen Liu, Jian Lu, Regioisomerized atom transfer radical addition (ATRA) of olefins with dichlorofluorocarbons, RSC Adv., 2015, 5, 101412-101415.

16:Ju-You Lu,Hong Wan, Jianwei Zhang,Zhixuan Wang,Yang Li,Yongmei Du,Chunying Li,Zhao-Tie Liu,Zhong-Wen Liu,Jian Lu, Palladium-Catalyzed Direct Cross-Coupling of Carboranyllithium with (Hetero)Aryl Halides, Chem. Eur. J., 2016, 22, 17542-17546.

17:Wei Lu,Yang Li, Dong Xue, Chao Wang and Jianliang Xiao,Pd-catalyzed carbonylation for the construction of tertiary and quaternary carbon centers with sp3carbon partners,Org. Biomol. Chem.,2014,12, 5243-5249.

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